![]() Plant for the absorption of individual components from gases
专利摘要:
The subject of this invention is a plant (1) for the absorption of individual components such as pollutants or valuable substances in gases, in which an absorption solution in an absorption space (3) is brought into contact with the gas, wherein the absorption solution via spray nozzles (20) into the absorption space (3) is introduced and the gas via a vertical inlet channel (5) from below the absorption space (3) is supplied, wherein the inlet channel (5) by a roof attachment (13) is covered. According to the invention, the roof attachment (13) is constructed from a multiplicity of lamellae (14) arranged one above the other and spaced apart from one another. 公开号:AT520534A4 申请号:T50330/2018 申请日:2018-04-19 公开日:2019-05-15 发明作者:Koller Martin;GURKER Thomas 申请人:Andritz Ag Maschf; IPC主号:
专利说明:
Summary The subject of this invention is a system (1) for the absorption of individual components such as pollutants or valuable substances in gases, in which an absorption solution in an absorption space (3) is brought into contact with the gas, the absorption solution being sprayed into the absorption space (20) (3) is introduced and the gas is fed via a vertical inlet channel (5) from below to the absorption space (3), the inlet channel (5) being covered by a roof attachment (13). According to the invention, the roof attachment (13) is constructed from a plurality of slats (14) which are arranged one above the other and spaced apart from one another. / 17th 7258-AT SYSTEM FOR ABSORPTION OF INDIVIDUAL COMPONENTS IN GASES The subject of this invention is a system for the absorption of individual components (e.g. pollutants or valuable substances) in gases, in which an absorption solution is brought into contact with the gas in an absorption space. The absorption solution is introduced into the absorption space via spray nozzles. The gas is supplied to the absorption space from below via a vertical inlet channel, the inlet channel having an opening which is covered by a spaced roof attachment. The floor plan of the roof attachment is larger than the floor plan of the inlet opening so that the absorption solution cannot drip into the inlet opening. Many industrial processes, especially combustion processes, produce exhaust gases or exhaust air that contain acidic components such as sulfur dioxide (S02), hydrochloric acid (HCl), hydrogen fluoride (HF) and / or nitrogen oxides (NO, N02), which are harmful to the environment Ecosystem are called pollutants or also valuable materials, such as Metal oxides that are brought into a gaseous state by the treatment process. Various technologies for so-called wet exhaust gas and flue gas treatment are already known from the prior art, in which the absorption space is designed as a spray tower in the form of a drop column. There are stationary systems that are mainly used for the flue gas cleaning of power plants, but there are also known mobile systems that clean the exhaust gases of an internal combustion engine. 2.17 7258-AT The current state of the art of mobile exhaust gas cleaning systems, for example for ships, is technologically derived from stationary systems. The exhaust gas is either fed to the scrubber (absorption space) through a side opening or it is introduced into the scrubber from below. The shield against the dispersed washing liquid (absorption solution) is provided by a single canopy (Chinese hat) placed on the entry channel. The lateral gas inlet in mobile systems represents the direct technical change of the stationary design and is considered a technically unobjectionable solution Pulling up the channel and constructing an artificial one Gradient towards the washer the danger of a Passage of the scrubbing liquid into the exhaust tract can be largely prevented. In contrast to the stationary However, solutions are larger Safety reserves should be planned as slug currents (e.g. by heeling a ship) must be taken into account. A disadvantage of the side flue gas inlet is the large space required for the side Introduction of the Exhaust in the Washer. The Feed channel channel is transferred from the vertical axis via a generous deflection bend into a horizontal channel piece, the underside of the channel being equipped with a clear slope or weir to prevent the above-mentioned liquid entry. Since the exhaust gas is introduced into the lower part of the scrubber, the installation area of the scrubber is doubled depending on the design. / 17th 7258-AT The vertical gas supply in the scrubber with a simple roof attachment (Chinese hat) is a structurally attractive alternative to the side entry, but in general there is no complete protection against the passage of the washing liquid into the exhaust system and can only be used safely in special cases. In practice, the pressure loss is greatly increased by using the simple roof attachment, because the gas flow through the roof attachment is deflected twice and the sides of the roof have to be stroked in a narrow radius. This constriction means that only a small part of the available free passage area is used. The rest of the channel cross section is either insufficiently flowed through or a recirculation zone is formed. The latter affects the local pressure conditions in such a way that parts of the free cross-section are flowed through in the opposite direction. This means that there is a risk that drops will be entrained in the exhaust line. The associated increase in pressure loss means that the requirements of the overall system cannot be met or that the economic operation of the system is significantly deteriorated. The aim of the invention is to provide a flue gas or exhaust gas purification system which requires the smallest possible footprint, in which the pressure loss occurring is minimized and in which a drop of the absorption solution passes into the flue gas or. Exhaust system is largely excluded. This problem is solved by a system according to claim 1. The vertical gas inlet allows 4.17 7258-AT minimize the necessary installation area of the cleaning system and the pressure drop that occurs is kept low by the roof attachment according to the invention, which is constructed from a plurality of slats arranged one above the other and spaced apart from one another. By choosing a vertical instead of a lateral washer inlet, the space required can be reduced to about half. This is an advantage in planning, especially in the case of mobile systems, such as when used on ships. Even clearer advantages result when retrofitting existing exhaust systems, since the compact system can be easily integrated into the existing structure. The system according to the invention is particularly suitable for cleaning ship exhaust gases. The pollutants are removed from the exhaust gases with the help of sea water, if necessary by adding sodium hydroxide solution or sodium carbonate. The slats preferably run obliquely downwards towards the wall of the absorption space. Ideally with an angle of inclination α of 50 ° to 70 °, preferably 60 °. This area results in the optimal compromise between adequate protection against liquid entry into the inlet duct and as little gas deflection as possible to reduce the pressure loss. It makes sense if the length of the channels between the slats is greater than the distance between the slats forming the channels. This also prevents liquid from entering the inlet channel. / 17th 7258-AT The roof attachment can be pyramidal or conical, for example. In a preferred embodiment, a gas distribution level is arranged above the roof attachment. This gas distribution level, on the one hand, makes the gas supplied more uniform and, on the other hand, creates a highly turbulent suspension regime (liquid layer). The gas distribution level can consist, for example, of a large number of pipes connected to one another. It is favorable if the lamellae are curved in the direction of the gas inlet in their initial area, since this supports the gas deflection and the pressure loss is further reduced. The invention is described below with reference to drawings. Show it: Fig. 1 shows an exemplary embodiment of the system according to the invention; 2 shows a side view of a roof attachment according to the invention; 3 shows a plan view of the roof attachment from FIG. 2; Figure 4 is a sectional view taken along line A-A of Figure 3; 5 shows a further sectional view along the line B-B from FIG. 3; 6 shows a detailed view of the roof attachment according to FIG. 5; Fig. 7 is a schematic representation of the roof attachment; 6.17 7258-AT The same reference numerals in the individual figures denote the same parts of the system. 1 shows a cross section through an exhaust gas cleaning system 1 according to the invention. The exhaust gas flows in the vertical direction 6 via the inlet channel 5 from below into the preferably cuboidal absorption space 3, which is delimited by the container wall 10. Compared to systems with side entry, this results in a reduction in the footprint of the exhaust gas cleaning system, which largely depends on the design of the scrubber inlet. The exhaust gas flows through the absorption space 3 from bottom to top and leaves it through the gas outlet 2. The opening 12 of the inlet channel 5 is covered by a pyramid-shaped roof attachment 13 with a square base. The gas distribution level 7, which consists of a large number of individual tubes 11, is located directly above the roof attachment 13. The gas distribution level 7 distributes the exhaust gas more evenly within the absorption space 3 and also induces turbulence in the flue gas, which leads to more intensive mixing of the gas with the absorption solution. The absorption solution is introduced into the absorption space 3 via spray nozzles 20 of the spray levels 4 and comes into contact with the exhaust gas in drop form. The roof attachment 13 prevents the absorption solution from entering the inlet duct 5 and thus the exhaust tract. A rinsing device 8 and a droplet separator 9 are provided above the spray levels 4. 7.17 725 8-AT In Figure 2, the roof attachment 13 is shown in a side view. It consists of a plurality of lamellae 14 arranged one above the other, which are spaced apart from one another, so that the exhaust gas reaches the absorption space 3 through the channels 15 formed between the lamellae 14. The gas flow, which initially runs vertically, is deflected in the distributor space within the roof attachment 13 in the direction of the slats 14 in such a way that the passage surfaces are evenly loaded. The flanks of the roof attachment 13 are tapered towards the top and meet at one point or in a small, overhead auxiliary roof 19. The primary goal of this arrangement is to maximize or optimize the passage area for the inflowing branch. Flue gas in the absorption room 3. The secondary aim of this arrangement compared to vertically arranged roof flanks is that the roof attachment 13, which tapers upwards, provides additional space for the throughflow. By increasing the freely flowable area, the exhaust gas or flue gas is braked immediately after it leaves the lamellae 14 and quickly deflected upwards. In contrast to the redirection with a Chinese hat, in which the flow rises unevenly in the form of strands, the turn-off increases here. Flue gas in the sense of a plug flow freely upwards. FIG. 3 shows a top view of the roof attachment 13. One can see here the struts 18 which connect the individual slats 14 at their outer ends, thereby preventing the slats 14 from fluttering. 8.17 7258-AT In Figures 4 and 5 are sections along the Lines Ά-Ά and B-B (see Figure 3) shown. FIG. 6 shows a detailed view of the roof attachment 13 from FIG 5. The fins 14 here have an arcuate curved starting area 16 in the direction of the gas inlet. As a result, the gas can flow evenly between the individual lamellae 14 along the deflection, and local separation or recirculation after the deflection is prevented. The gas flow is indicated by the two arrows 17. This optimized flow control significantly minimizes pressure loss compared to the Chinese hat solution. Figure 7 shows a schematic view of the roof attachment to illustrate individual dimensions and angles. Studies have shown that the relationship between the cross-sectional area of the inlet channel 5 and the Cross-sectional area of the absorption space 3 (measured at the height of the opening 12) should be between 0.3 and 0.5. The diameter D of the inlet channel 5 is here, for example, 1500 mm. The distance h of the lowest slat from the scrubber floor is 500 mm. The length y of the lamella 14 and the lamella spacing x are selected such that a drop entry against the outflow direction is prevented. The length y of the slats 14 is preferably between 150 and 300 mm, the slat spacing x should be between 40 and 60 mm, preferably 50 mm. The slats 14 of the auxiliary roof 19 have a length z of 290 mm here. The angle of attack α of the individual slats 14 with respect to a vertical should be 50 ° to 70 °, preferably 60 ° 9.17 7258-AT. This angle a. was chosen with regard to the pressure loss so that the required deflection against the actual main flow direction is reduced to a minimum. The angle β of the roof slope 21 should be in the range from 140 ° to 170 °, preferably 155 °, with respect to a vertical. For stable operation, it is advantageous if the gas speed in the inlet duct 5 is 14-18 m / s, since significantly higher or lower flow speeds would lead to poor flow distribution within the roof attachment 13. The gas velocity in the channels 15 should be in the range of 7 to 13 m / s. 10/17 7258-AT
权利要求:
Claims (9) [1] claims 1.System (1) for the absorption of individual components such as pollutants or valuable substances in gases, in which an absorption solution is brought into contact with the gas in an absorption space (3), the absorption solution being applied via spray nozzles (20) to a spray level (4) Absorption space (3) is introduced and the gas can be fed from below to the absorption space (3) via a vertical inlet duct (5), the inlet duct (5) having an opening (12) which is covered by a roof attachment (13), wherein the floor plan of the roof cap (13) is larger than the floor plan of the inlet opening (12) so that the absorption solution does not fall into the inlet opening (12), characterized in that the roof cap (13) consists of a plurality of slats (one above the other and spaced apart) 14) is constructed. [2] 2. Plant according to claim 1, characterized in that the slats (14) to the container wall (10) of the absorption space (3) run obliquely downwards, so that the vertically inflowing gas is deflected obliquely downwards and through between the slats (14 ) formed channels (15) can be fed to the absorption space (3). [3] 3. Plant according to claim 2, characterized in that the angle α between the slats (14) and the vertical between 50 ° and 70 °, preferably 60 °. [4] 4. Plant according to claim 2 or 3, characterized in that the length (y) of the channels (15) between two 11/17 7258-AT Slats (14) is greater than the distance (x) of the slats (14) forming the channels (15). [5] 5. Installation according to one of claims 1 to 4, characterized in that the slope (β) of the roof flank is based on a vertical between 140 ° and 170 °, preferably 155 °. [6] 6. Installation according to one of claims 1 to 5, characterized in that the slats (14) form a pyramid-shaped roof attachment (13). [7] 7. Installation according to one of claims 1 to 5, characterized in that the slats (14) form a conical roof attachment (13). [8] 8. Installation according to one of claims 1 to 7, characterized in that a gas distribution plane (7) is arranged above the roof attachment (13), caused by the turbulence in the supplied gas stream. [9] 9. Plant according to one of claims 1 to 8, characterized in that the lamellae (14) are curved in an arcuate manner in their initial region (16), so that the deflection of the gas is thereby supported. 12/17 7258 AT 13/17 7258 AT 14/17 7258 AT Section A-A
类似技术:
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同族专利:
公开号 | 公开日 US20190323409A1|2019-10-24| EP3556452A1|2019-10-23| CN110385016A|2019-10-29| PL3556452T3|2021-11-22| AT520534B1|2019-05-15| EP3556452B1|2021-03-31|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 DE2403472A1|1973-01-26|1974-09-05|Stanislas De Korvin|METHOD OF CLEANING UP BY WET SEPARATION AND EVACUATION OF GAS SUSPENDED MICRONIC LIQUID AND SOLID PARTICLES| DE9304777U1|1993-03-29|1994-06-09|Dolata Tilo Dipl Ing|Multipurpose gas washer| WO1996004065A1|1994-07-29|1996-02-15|Steag Aktiengesellschaft|Adsorption reactor for separating undesirable components from a fluid| KR20010112081A|2001-06-02|2001-12-20|이동일|Harmful material exclusion apparatus using ramella separator activated carbon fiber and wet washing machine|CN111804133A|2020-07-20|2020-10-23|中国船舶电站设备有限公司|Closed desulfurization system for seawater of ship|GB120304A|1918-01-04|1918-11-07|Robert Stuart Hilton|Improvements in and relating to Apparatus for Bringing Gases and Liquids into Intimate Contact.| JPS4631321B1|1968-10-08|1971-09-11| CN201988311U|2010-12-20|2011-09-28|詹清光|Waste gas treatment device| CN102852596A|2011-07-01|2013-01-02|彭斯干|Method, device and system for optimizing exhaust back pressure of internal combustion engine| AT512543B1|2012-07-17|2013-09-15|Andritz Energy & Environment Gmbh|Plant and method for absorbing individual components in gases| KR101448459B1|2012-12-07|2014-10-08|주식회사 포스코플랜텍|Wet scrubber| CN103041687B|2012-12-18|2015-05-06|北京威肯众合环保科技有限公司|Oil furnace flue gas purification compound tower integrating dust removal, smoke abatement and desulphurization| KR101608720B1|2015-02-27|2016-04-04|부경대학교 산학협력단|Exhaust gas purification system| AT14588U1|2015-03-05|2016-02-15|Andritz Ag Maschf|Lifting device for gas distribution modules| CN205495321U|2016-04-08|2016-08-24|浙江科技学院|Dedusting desulfurization tower| EP3260187A1|2016-06-23|2017-12-27|Yara Marine Technologies AS|System and method for reducing the amount of sulfur oxides in exhaust gas| CN106512641A|2016-12-03|2017-03-22|福建众辉环保设备有限公司|Purifying device for organic exhaust gas|AT523037B1|2020-02-07|2021-05-15|Avl List Gmbh|WET WASHER FOR GASES|
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申请号 | 申请日 | 专利标题 ATA50330/2018A|AT520534B1|2018-04-19|2018-04-19|Plant for the absorption of individual components from gases|ATA50330/2018A| AT520534B1|2018-04-19|2018-04-19|Plant for the absorption of individual components from gases| EP19156841.9A| EP3556452B1|2018-04-19|2019-02-13|Device for the absorption of individual components in gases| PL19156841T| PL3556452T3|2018-04-19|2019-02-13|Device for the absorption of individual components in gases| US16/375,226| US20190323409A1|2018-04-19|2019-04-04|Plant for Absorption of Individual Components in Gases| CN201910315276.1A| CN110385016A|2018-04-19|2019-04-18|Absorb the equipment of the individual components in gas| 相关专利
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